A Highly Connected Porous Coordination Polymer
with Unusual Channel Structure and Sorption Properties

Yue-Biao Zhang, Wei-Xiong Zhang, Fei-Yue Feng, Jie-Peng Zhang,* and Xiao-Ming Chen*
Angew. Chem. Int. Ed. 200948, 5287–5290.
Making connections: A hydroxy‐centered trinuclear nickel cluster has been employed to construct a highly connected, highly symmetric framework with a uninodal nine‐connected topology. An array of triakis tetrahedra leads to a biporous intersecting‐channel system.